pK values from acidity function type methods inherent uncertainties
The uncertainties inherent in the measurement of thermodn. pK values by means of excess acidity functions are examd. by using a statistical approach. The key to the problem is the math. form of the equation relating the activity coeffs. of 2 weak bases. The anal. presented here, using data for 10 we...
|Journal Title:||Journal of Physical Chemistry Vol. 89; no. 9; pp. 1748 - 1752|
|Author:||John F. Wojcik|
|Application Date:||Dep. Chem.,Villanova Univ.,Villanova,PA,USA.|