Oxidation of amines with 2-sulfonyloxaziridines (Davis' reagents).

2-(Phenylsulfonyl)-3-aryloxaziridines (Davis' reagents) react rapidly with amines that are more basic than pyridine to give products that are dependent upon the structure of the amine. Tertiary aliph. amines are oxidized to the corresponding N-oxides in high yields, while secondary aliph. amines giv...

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Journal Title: Journal of Organic Chemistry Vol. 53; no. 25; pp. 5856 - 5860
Authors: Walter W. Zajac, Thomas R. Walters, Michael G. Darcy
Format: Article
Published: 1988
Application Date: Dep. Chem.,Villanova Univ.,Villanova,PA,USA.
Subjects: