Oxidative Intramolecular Cyclization of Diketoximes: Synthesis of 1,5-Dinitro-cis-bicyclo[3.3.0]octane.

The dioximes of 1,5-cyclooctanedione, bicyclo[3.3.1]nonane-3,7-dione and 9,9-dimethoxybicyclo[3.3.1]nonane-3,7-dione underwent oxidative cyclization using 3-chloroperoxybenzoic acid in hot acetonitrile to yield 1,5-dinitro-cis-bicyclo[3.3.0]octane, 3,7-dinitronoradamantane and 9,9-dimethoxy-3,7-dini...

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Journal Title: Journal of Organic Chemistry Vol. 61; no. 10; pp. 3545 - 3547
Authors: Walter W. Zajac, Thomas R. Walters, John H. Buzby, Gary J. Speier
Format: Article
Published: 1996
Application Date: Department of Chemistry,Villanova University,Villanova,PA,USA.