alpha -Nitro ketones. 2. Conformational equilibriums of 2-nitrocyclohexanones.

Dipole moment and 1H NMR data indicate the conformational free energy of the nitro group in 2-nitrocyclohexanone to be 1.26-1.39 kcal/mol (.apprx.90% equatorial). The conformations of several nitrocyclohexanones were detd.

Journal Title: Journal of Organic Chemistry Vol. 45; no. 21; pp. 4154 - 4157
Authors: Walter W. Zajac, Hadi Ozbal
Format: Article
Published: 1980
Application Date: Dep. Chem.,Villanova Univ.,Villanova,PA,USA.
Subjects:
NMR