Relative reactivities of cycloalkanone dimethyl ketals to hydrogenolysis by dichloroaluminum hydride.
The relative rate of hydrogenolysis of a series of cycloalkanone dimethyl ketals by AlCl2H to the corresponding cycloalkyl Me ethers were detd. The order of reactivity varies with ring size in the following manner: C7 > C8 > C9 ~ C5 > C11 ~ 3-pentanone > C10 > C6 > C12 > C4. These results are consis...
|Journal Title:||Journal of Organic Chemistry Vol. 35; no. 10; pp. 3375 - 3377|
|Authors:||Walter W. Zajac, Kevin J. Byrne|
|Application Date:||Dep. of Chem.,Villanova Univ.,Villanova,PA,USA.|
Acetals Role: RCT (Reactant), RACT (Reactant or reagent) (hydrogenolysis of, mechanism of catalytic)
Aluminum chloride hydride Role: CAT (Catalyst use), USES (Uses) (catalysts, for hydrogenolysis of cycloalkanone dimethyl ketals)