Hydrogenolysis of acetals and ketals by alkoxyalanes and alkoxychloroalanes.
Hydrogenolysis of acetals, ketals, and 1,3-dioxolanes was examd. using alkoxy substituted alanes. Alkoxychloroalanes are moderately reactive and show potential as stereoselective reducing reagents. Alkoxyalanes were less reactive and dialkoxyalanes too unreactive for hydrogenolyses.
|Journal Title:||Journal of Organic Chemistry Vol. 38; no. 2; pp. 384 - 387|
|Authors:||Walter W. Zajac, Kevin J. Byrne|
|Application Date:||Dep. Chem.,Villanova Univ.,Villanova,PA,USA.|