Syntheses of oligometalloles by catalytic dehydrocoupling

The dehydrocoupling polycondensation of dihydro(tetraphenyl)metalloles (M = Si or Ge) with 0.2 mol % H2PtCl6 center dot xH(2)O and excess cyclohexene produces the respective oligometallole in high yield (> 80%), where every silicon or germanium atom of the oligomer backbone is part of a silole or ge...

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Journal Title: Organometallics Vol. 24; no. 13; pp. 3081 - 3087
Authors: Scott Kassel, A. L. Rheingold, S. J. Toal, H. Sohn, L. N. Zakarov, J. A. Golen, W. C. Trogler
Format: Article
Language: English
Published: 2005
JUN 20