Nazarov Approach to 4-Benzoyloxymethyl-cyclopent-2-enone, a Precursor to the Helminthosporols
| Author(s): | Eduard Casillas, Heidi Shimp, Steven Clareen, Lindsay Curtis, Nicole Simonowicz, Justin Belardi, Catherine Leimkuhler |
|---|---|
| Year of Publication: | 2005 |
| Journal Title: | Synthetic Communications |
| ISSN: | 0039-7911 |
| Volume: | 35 |
| Issue: | 12 |
| Date Name: | Jun 2005 |
| Start Page: | 1633 |
| Abstract: | A short, scalable route to 4-hydroxymethylcyclopent-2-enone, based upon a silicon-directed Nazarov cyclization, is described. Noteworthy in this study is the success of the cyclization with an oxygenated substrate |
| End Page: | 1640 |
| Subjects: |
BF3-etherate
CONVENIENT ROUTE KHAND REACTION CHEMISTRY, ORGANIC CYCLIZATIONS divinylcyclopropane rearrangement silicon-directed Nazarov REARRANGEMENT |
| Digital Object Identifier: | 10.1081/SCC-200061633 |
| Link to Full Text: | Full Text |
