Silica Promoted Diels-Alder Reactions in Carbon Dioxide from Gaseous to Supercritical Conditions
Amorphous fumed silica (SiO2) was shown to increase yields and selectivities of several Diels-Alder reactions in gaseous and supercritical CO2. Pressure effects on the Diels-Alder reaction were explored using methyl vinyl ketone and penta-1,3-diene at 80 C. The selectivity of the reaction was not af...
|Journal Title:||Journal of Physical Chemistry Vol. 103; no. 15; pp. 2878 - 2887|
|Authors:||J.W. Tester, R.L. Danheiser, A.S. Renslo, Randy Weinstein|