Synthesis of lemonose derivatives methyl 4-amino-3-O,4-N-carbonyl-2,4,6-trideoxy-3-C-methyl-α-l-lyxo-pyranoside and its phenyl thioglycoside
Lemonose is a component of the antibiotic lemonomycin and other antibiotics and natural products. Three routes to the synthesis of the title compound, a protected, desmethyl derivative of lemonose, from l-rhamnose or its glycal, were investigated based on electrophilic cyclization, epoxidation-ring...
|Journal Title:||Carbohydrate Research Vol. 409; pp. 63 - 68|
|Authors:||Walter J. Boyko, Robert M. Giuliano, W. Scott Kassel, Nicholas A. Piro, Alicia C. Briegel, Adrienne K. Cummings, Garry R. Smith, Matthew D. Doroski|