Polymerization with Redox Initiators. V. Substituent Effects in the Initiator System Diethylanilene-Benzoyl Peroxide.
The kinetics of the polymerization of styrene initiated by the system benzoyl peroxide--substituted diethylanilene has been studied at 30 [degrees] Celsius. The rate constant for the induced decomposition of the peroxide is found to depend on the amine basicity and is correlated wi the Hammet [sigm...
|Journal Title:||Sonderdruck aus Die Makromolekulare Chemie Vol. 47; no. 1; pp. 15 - 18|
|Authors:||Kenneth F. O'Driscoll, E. N. Ricchezza|