Polymerization with Redox Initiators. V. Substituent Effects in the Initiator System Diethylanilene-Benzoyl Peroxide.

The kinetics of the polymerization of styrene initiated by the system benzoyl peroxide--substituted diethylanilene has been studied at 30 [degrees] Celsius. The rate constant for the induced decomposition of the peroxide is found to depend on the amine basicity and is correlated wi the Hammet [sigm...

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Journal Title: Sonderdruck aus Die Makromolekulare Chemie Vol. 47; no. 1; pp. 15 - 18
Authors: Kenneth F. O'Driscoll, E. N. Ricchezza
Format: Article
Language: English
Published: Heidelberg : Huthig Verlag, 1961
April 1961